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Additional resources for Fluorinated Coatings and Finishes Handbook: The Definitive User's Guide (Plastics Design Library Handbook Series)

Example text

4 Ethylene-Chlorotrifluoroethylene (E-CTFE) Copolymer E-CTFE is a copolymer of ethylene and chlorotrifluoroethylene. The following is the molecular structure of E-CTFE (see also Fig. 9): This simplified structure shows the ratio of the monomers being 1-1 and strictly alternating, but this is not required. Commonly known by the tradename, Halar®, E-CTFE is an expensive, melt processable, semicrystalline, whitish semi-opaque thermoplastic with good chemical resistance and barrier properties. It also has good tensile and creep properties and good high frequency electrical characteristics.

These factors have spurred research into carbon dioxide as a safe, functional, and economical reaction medium. 1 shows models of three possible fluoropolymer endgroups. The first one is a fully fluorinated endgroup of –CF3. A process for producing this endgroup has been patented by DuPont. The last two models show common fluoropolymer endgroups that are reactive and will also decompose at lower temperatures. 1 Models of fluoropolymer endgroups. 4 Finishing As-produced dispersions are called raw because PTFE dispersion out of the reactor is of little use.

7. Generally there are other dispersions available, but they may not appear on lists of those freely available. 3 20 Fine Powder Production Most fine PTFE powders are used in molding applications rather than coating applications, though the use of these powders in coatings is not out of the realm of possibility. To produce fine powder from the polymerization dispersion, three processing steps have to take place. 1. Coagulation of the colloidal particles. [37] Friction or contact between the particles, especially at a high temperature, adversely affects the fine powder because of easy fibrillation and loss of its particulate structure leading to poor properties of parts made from this resin.

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