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3. 4. 5. 6. 7. 8. 9. 10. G. Kalb, Z. , 74:65 (1930). G. M. Virovlyanskii, Zap. Vses. Min. , ser. 2, 67(3):446 (1938). V. D. Kuznetsov, Crystals and Crystallization [in Russian], Gostekhteorizdat, Moscow (1953). G. G. Lemmlein, Trudy Lomonosov. Inst. Akad. 6, 13 (1935). J. Dana, E. S. Dana, and C. Frondel, System of Mineralogy: Vol. 3, Silicon Minerals [Russian translation], Mir, Moscow (1966). V. P. Butuzov, A. N. Kovalevskii, and L. A. Samoilovich, Trudy VNII Sint. Min. Syr'ya, Vol. 6 (1962). G.

A more detailed study of the stability of the alkali germanates enables one to define more closely the role of the A cations, as in beryllium, where the steric factor is the principal one. 2-4 A, which allows large cations such as Cs and K Fig. 5. Structure of zeolitic A3HGe7016 . 4H20 in projection on (001) showing groups of four Ge octahedra and empty channels. *At T > 185°C one gets only GeOz(t) with Ge in sixfold coordination, which indicates that the solution under hydrothermal conditions contains not Ge(OH)4tetr but Ge(OH)6oct' or even complexes consisting of 2, 3, 4, or more octahedra.

F. Kashkurov, and A. V. Simonov, Kristallografiya, 13(3):559 (1968). T. G. Petrov, Kristallografiya, Vol. 4 (1964). V. A. Kuznetsov, in: Hydrothermal Synthesis of Crystals, Consultants Bureau, New York (1971), p. 52. A. A. Chernov and V. A. Kuznetsov, Kristallografiya, Vol. 5 (1969). FEATURES OF AMETHYST CRYSTALS SYNTHESIZED IN THE K20-C0 2 -Si02 -H 20 SYSTEM E. M. Tsyganov, V. E. Khadzhi, A. A. Shaposhnikov, M. I. Samoilovich, and L. I. Tsinober Synthetic amethysts may be made hydrothermally in the system K20-C~-Si~ -H20 in the presence of iron [1,2]; when the (R) and (r) pyramids of such crystals are exposed to ionizing radiation,* they acquire an amethyst color, and the strength of the color in the (R) pyramid is usually much greater than that in the (r) pyramid.

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